AGP/CBH/HSA

Protein Based Chiral Columns from Daicel

Columns packed with the immobilized protein stationary phases (PSPs) are successfully utilized by scientists for separation and characterization of chiral compounds in a great number of applications, ranging from drug discovery and quality assurance of marketed drugs to environmental monitoring.

The chiral selector for the CHIRALPAK AGP is α1-acid glycoprotein (AGP), while human serum albumin (HSA) is the chiral selector for CHIRALPAK HSA. The chiral selector for CHIRALPAK CBH is cellobiohydrolase, a stable enzyme. The three chiral selectors are immobilized on 5-µm spherical silica particles. The PSPs function entirely in the reversed-phase chromatographic mode, using buffers with low organic modifier content and at moderate pH values. Enantioselectivity can easily be controlled or improved by changes in the mobile phase composition: pH, buffer and organic modifier types and concentrations.

All PSP selectors are packed in columns with 3, 4 and 10 mm internal diameter to cover separations on both analytical and semi-preparative scales.

AGP/CBH/HSA

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Features

CHIRALPAK AGP

  • Chiral selector is alpha1-acid glycoprotein
  • Separates enantiomers of an extremely broad range of drug compounds including amines, acids, amides, esters, alchohols and sulfoxides

CHIRALPAK CBH

  • Chiral selector is cellobiohydrolase
  • Separation of enantiomers of basic drugs from many compound classes
  • Separates preferentially compounds containing one or more basic nitrogen's together with one or more hydrogen accepting or hydrogen donating groups (alcohol, phenol, carbonyl, amide, ether, sulphoxide, ester)

CHIRALPAK HSA

  • Chiral selector is human serum albumin
  • Especially suited for the separation of weak and strong acids, zwitterionic and nonprotolytic compounds
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